Product ID:A-100 EXTERIOR SATIN LATEX PAINT WHITE, (SUPDAT)
MSDS Date:11/29/1995
FSC:8010
NIIN:00N038463
MSDS Number: CFNVN

SHERWIN-WILLIAMS CO

101 PROSPECT AVE NW
CLEVELAND, OH 44115
US

Emergency Phone: 216-566-2917

Info Phone: 216-566-2902

Cage: 54636

SHERWIN-WILLIAMS CO THE

CLEVELAND, OH 44115-1042 US

Telephone: 800-251-2486/216-566-2242

Cage: 54636

DRINKING WATER OR BY GAVAGE. THERE IS NO EVIDENCE TO

RTECS: 9999999ZZ

OVEREXPOSURE TO SOLVENT INGREDIENTS MAY CAUSE ADVERSE

RTECS: 9999999ZZ

TITANIUM DIOXIDE DUST @ 250 MG/M3 DEVELOPED LUNG

RTECS: 9999999ZZ

WORKPLACE.

RTECS: 9999999ZZ

SPECIFIC DUSTS ARE LISTED IN INGREDS, THE APPLIC

RTECS: 9999999ZZ

(TOTAL DUST), OSHA PEL 15 MG/M3 (TOTAL DUST), 5

RTECS: 9999999ZZ

DUST WHICH MAY BE GENERATED FROM THIS PRODUCT,

RTECS: 9999999ZZ

OSHA STANDARDS 1910.94, 1910.107, 1910.108.

RTECS: 9999999ZZ

0.12

CAS: 107-21-1

RTECS: KW2975000

Fraction By Weight: 2%

OSHA PEL N/K

ACGIH TLV: C 50 PPM, VAPOR

EPA Report Quantity: 1 LB

DOT Report Quantity: 1 LB

SILICA, CRYSTALLINE - CRISTOBALITE

CAS: 14464-46-1

RTECS: VV7325000

Fraction By Weight: 0.6%

OSHA PEL SEE TABLE Z-3

ACGIH TLV: 0.05 MG/M3 RDUST

CLAY (KAOLIN)

CAS: 1332-58-7

RTECS: GF1670500

Fraction By Weight: 2%

OSHA PEL 15 MG/M3 TDUST

ACGIH TLV: 2 MG/M3 TDUST

TITANIUM OXIDE; (TITANIUM DIOXIDE)

CAS: 13463-67-7

RTECS: XR2275000

Fraction By Weight: 19%

OSHA PEL 15 MG/M3 TDUST

ACGIH TLV: 10 MG/M3 TDUST

ZINC OXIDE (SARA 313) (CERCLA)

CAS: 1314-13-2

RTECS: ZH4810000

Fraction By Weight: 2-3%

OSHA PEL 15 MG/M3 TDUST

ACGIH TLV: 10 MG/M3 TDUST

LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO
Health Hazards Acute and Chronic:ACUTE:EXPOS MAY BE BY INHAL AND/OR
SKIN/EYE CONT, DEPENDING ON CNDTNS OF USE. TO MINIMIZE EXPOS,
FOLLOW REC FOR PROPER USE, VENT, & PERSON PROT EQUIP. EFTS OF
OVEREXP:IRRIT OF EYES, SKIN & UPPER RESP SYS. IN CONFINED AREA
VAPS IN HIGH CONCS MAY CAUSE HDCH, NAUS/DIZZ. SIGNS & SYMPS OF
OVEREXP:REDNESS (EFTS OF OVEREXP)
Explanation of Carcinogenicity:SILICA, CRYSTALLINE-CRISTOBALITE: IARC
MONO, VOL 68, 1997: GROUP 1. NTP 7TH ANNUAL RPT ON CARCIN,
1994:ANTIC (SUPDAT)
Effects of Overexposure:HLTH HAZ:& ITCHING/BURNING SENSATION MAY
INDICATE EYE/EXCESS SKIN EXPOS. CHRONIC:CRYSTALLINE SILICA (QUARTZ,
CRISTOBALITE) IS LISTED BY IARC & NTP. LONG TERM EXPOS TO HIGH
LEVELS OF SILICA DUST, WHICH CAN OCCUR ONLY WHEN SANDING/ABRADING
DRY FILM, MAY CAUSE LUNG DMG (SILICOSIS) & POSSIBLY CANCER.
ETHYLENE (SUPDAT)
Medical Cond Aggravated by Exposure:NONE GENERALLY RECOGNIZED

First Aid:INHAL: REMOVE FROM EXPOSURE. RESTORE BREATHING. KEEP WARM &
QUIET. SKIN: WASH AFFECTED AREA THOROUGHLY W/SOAP & WATER. REMOVE
CONTAMD CLOTHING & LAUNDER BEFORE RE-USE. EYES: FLUSH W/LARGE
AMOUNTS OF W ATER FOR @ LST 15 MINUTES. GET MEDICAL ATTENTION.
INGEST: GET MEDICAL ATTENTION.

Extinguishing Media:CARBON DIOXIDE, DRY CHEMICAL, ALCOHOL FOAM.
Fire Fighting Procedures:NIOSH APPRVD SCBA & FULL PROT EQUIP . WATER
SPRAY MAY BE INEFTIVE. IF WATER IS USED, FOG NOZZ ARE PREF. WATER
MAY BE USED TO COOL CLSD CNTNRS TO (SUPDAT)
Unusual Fire/Explosion Hazard:CLOSED CONTAINERS MAY EXPLODE (DUE TO THE
BUILD-UP OF PRESSURE) WHEN EXPOSED TO EXTREME HEAT.

Spill Release Procedures:REMOVE ALL SOURCES OF IGNITION. VENTILATE AND
REMOVE WITH INERT ABSORBENT.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:KEEP CNTNR CLSD WHEN NOT IN USE.
TRANSFER ONLY TO APPRVD CNTNRS W/COMPLETE & APPROP LABELING. DO NOT
TAKE INTERNALLY. KEEP OUT OF REACH OF CHILDREN.
Other Precautions:USE ONLY W/ADEQ VENT. AVOID BRTHG VAP & SPRAY MIST.
AVOID CONT W/SKIN & EYES. THIS COATING MAY CONTAIN MATLS CLASSIFIED
AS NUISANCE PARTICULATES WHICH MAY BE PRESENT @ HAZ LEVELS ONLY
DURING SANDING/A BRADING OF DRIED FILM. IF NO (ING 11)

Respiratory Protection:IF PERSONAL EXPOS CANNOT BE CONTROLLED BELOW
APPLIC LIMITS BY VENT, WEAR PROPERLY FITTED ORG VAP/PARTICULATE
RESP APPRVD BY NIOSH FOR PROT AGAINST MATLS. WHEN SANDING/ABRADING
DRIED FILM, WEAR DUST/MI ST RESP APPRVD BY NIOSH FOR (ING 13)
Ventilation:LOC EXHAUST PREF. GEN EXHAUST ACCEPTABLE IF EXPOS TO MATLS
IS MAINTAINED BELOW APPLIC EXPOS LIMITS. REFER TO (ING 14)
Protective Gloves:IMPERVIOUS GLOVES .
Eye Protection:ANSI APPRVD CHEM WORKERS GOGGLES .
Other Protective Equipment:ANSI APPRVD EYE WASH & DELUGE SHOWER .
Work Hygienic Practices:WASH HANDS AFTER USING.
Supplemental Safety and Health
MFR TRADE NAME/PART NO:US AIR BASE. FIRE FIGHT PROC:PREVENT PRESSURE
BUILD-UP & POSS AUTOIGNIT/EXPLO WHEN EXPOSED TO EXTREME HEAT.
EXPLAN OF CARCIN:1994:TO BE CARCIN. EFTS OF OVEREXP:GLYCOL IS
CONSIDE RED AN ANIMAL TERATOGEN. IT HAS BEEN SHOWN TO CAUSE BIRTH
DEFECTS IN RATS & MICE @ HIGH DOSES WHEN GIVEN IN (ING 7)

Boiling Pt:B.P. Text:>212F,>100C
Vapor Pres:SEE INGS
Vapor Density:HVR/AIR
Spec Gravity:1.26
VOC Pounds/Gallon:112
pH:9.5
Evaporation Rate & Reference:SLOWER THAN ETHER
Solubility in Water:NOT APPLICALBE
Appearance and Odor:NONE SPECIFIED BY MANUFACTURER.
Percent Volatiles by Volume:67

Stability Indicator/Materials to Avoid:YES
NONE KNOWN.
Stability Condition to Avoid:NONE KNOWN.
Hazardous Decomposition Products:BY FIRE: CARBON DIOXIDE, CARBON
MONOXIDE.

Waste Disposal Methods:WASTE FROM THIS PROD IS NOT HAZ AS DEFINED UNDER
RCRA 40 CFR 261. INCINERATE IN APPRVD FACILITY. DO NOT INCINERATE
CLOSED CONTAINER. DISPOSE OF I/A/W FEDERAL, STATE, AND LOCAL
REGULATIONS REGARDING PO LLUTION.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.